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search_by_smiles

Find chemical compounds in PubChem's database using SMILES string queries for exact structure matching.

Instructions

Search for compounds by SMILES string (exact match)

Input Schema

TableJSON Schema
NameRequiredDescriptionDefault
smilesYesSMILES string of the query molecule

Implementation Reference

  • The handler function that executes the search_by_smiles tool: validates input, queries PubChem API for exact SMILES match, retrieves CID and details if found.
    private async handleSearchBySmiles(args: any) { if (!isValidSmilesArgs(args)) { throw new McpError(ErrorCode.InvalidParams, 'Invalid SMILES arguments'); } try { const response = await this.apiClient.get(`/compound/smiles/${encodeURIComponent(args.smiles)}/cids/JSON`); if (response.data?.IdentifierList?.CID?.length > 0) { const cid = response.data.IdentifierList.CID[0]; const detailsResponse = await this.apiClient.get(`/compound/cid/${cid}/property/MolecularFormula,MolecularWeight,CanonicalSMILES,IUPACName/JSON`); return { content: [ { type: 'text', text: JSON.stringify({ query_smiles: args.smiles, found_cid: cid, details: detailsResponse.data, }, null, 2), }, ], }; } return { content: [ { type: 'text', text: JSON.stringify({ message: 'No exact match found', query_smiles: args.smiles }, null, 2), }, ], }; } catch (error) { throw new McpError( ErrorCode.InternalError, `Failed to search by SMILES: ${error instanceof Error ? error.message : 'Unknown error'}` ); } }
  • Input schema definition for the search_by_smiles tool, returned in ListToolsRequestSchema handler.
    { name: 'search_by_smiles', description: 'Search for compounds by SMILES string (exact match)', inputSchema: { type: 'object', properties: { smiles: { type: 'string', description: 'SMILES string of the query molecule' }, }, required: ['smiles'], }, },
  • src/index.ts:744-745 (registration)
    Registration/dispatch case in CallToolRequestSchema handler that routes calls to the search_by_smiles handler.
    case 'search_by_smiles': return await this.handleSearchBySmiles(args);
  • Helper function for validating input arguments to search_by_smiles (and similar tools).
    const isValidSmilesArgs = ( args: any ): args is { smiles: string; threshold?: number; max_records?: number } => { return ( typeof args === 'object' && args !== null && typeof args.smiles === 'string' && args.smiles.length > 0 && (args.threshold === undefined || (typeof args.threshold === 'number' && args.threshold >= 0 && args.threshold <= 100)) && (args.max_records === undefined || (typeof args.max_records === 'number' && args.max_records > 0 && args.max_records <= 10000)) ); };

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