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submit_spin_states_workflow

Calculate energies for different spin multiplicities of molecules to analyze transition metal complexes, radical species, and magnetic properties.

Instructions

Submit a spin states workflow to calculate energies of different spin multiplicities.

FORMATTING NOTES (for MCP Inspector):

  • initial_molecule: Plain SMILES string (e.g., CCO, O=O)

  • states: JSON array without outer quotes (e.g., [[0,1], [0,3]])

Args: initial_molecule: SMILES string representing the molecule states: JSON array of [charge, multiplicity] pairs to calculate Multiplicity = 2S + 1 where S is total spin - Singlet (S=0): multiplicity = 1 (paired electrons) - Doublet (S=1/2): multiplicity = 2 (one unpaired electron) - Triplet (S=1): multiplicity = 3 (two unpaired electrons) - Quartet (S=3/2): multiplicity = 4 (three unpaired electrons) - Quintet (S=2): multiplicity = 5 (four unpaired electrons) solvent: Solvent environment, name or SMILES (default: empty for gas phase) name: Workflow name for identification and tracking folder_uuid: UUID of folder to organize this workflow. Empty string uses default folder. max_credits: Maximum credits to spend on this calculation. 0 for no limit.

Spin state calculations are essential for understanding:

  • Transition metal complexes and coordination chemistry

  • Radical species and open-shell molecules

  • Magnetic properties and spin crossover

  • Reaction mechanisms involving spin forbidden transitions

Returns: Workflow object representing the submitted workflow

Examples (MCP Inspector format): # Compare singlet and triplet states for oxygen initial_molecule: O=O states: [[0,1], [0,3]] name: O2 spin states

# Ethanol singlet and triplet (simple test) initial_molecule: CCO states: [[0,1], [0,3]] name: Ethanol spin states # Methylene carbene singlet and triplet initial_molecule: [CH2] states: [[0,1], [0,3]] name: Methylene spin states # Iron complex with multiple spin states initial_molecule: [Fe+2] states: [[2,1], [2,3], [2,5]] solvent: water name: Fe2+ aqueous spin states

Input Schema

TableJSON Schema
NameRequiredDescriptionDefault
initial_moleculeYesSMILES string of the molecule for spin state calculations
statesYesJSON array of [charge, multiplicity] pairs. Format: [[0,1], [0,3]] (no outer quotes)
solventNoSolvent environment for calculations (name or SMILES). Empty string for gas phase
nameNoWorkflow name for identification and trackingSpin States Workflow
folder_uuidNoUUID of folder to organize this workflow. Empty string uses default folder
max_creditsNoMaximum credits to spend on this calculation. 0 for no limit

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